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Mercurous Chloride is a water-insoluble mercury(I) chloride containing the dimeric Hg2(2+) cation. It is discussed in laboratory science in connection with electrochemical reference electrodes and the distinction between mercury(I) and mercury(II). The chemical designation and relevant molecular composition are important when interpreting reaction stoichiometry, chemical behaviour, and safety information. A notable property is the stable chloride-containing solid phase used in saturated calomel electrode systems. In scientific research, this substance is relevant primarily to controlled inorganic, analytical, or materials-chemistry investigations rather than routine unsupervised experiments. Specialist laboratories must account for mercury handling restrictions despite its low aqueous solubility, and trained staff should evaluate the actual procedure before use. The indicated LR Laboratory Reagent designation does not establish suitability for a specific quantitative method. This product listing refers to a 500 gram pack. Verify uncertain hydrate, polymorph, or color specifications before use.
Product Specifications
| Specification | Details |
|---|---|
| Appearance | White crystalline powder |
| Assay | 99% |
| Chemical Name | Mercury(I) chloride |
| Alternate Names | Calomel; dimercury dichloride; mercury subchloride |
| Molecular Formula | Hg2Cl2 |
| Empirical Formula | HgCl |
| CAS Number | 10112-91-1 |
| Molecular Weight | 472.08 g/mol |
| Grade | LR Laboratory Reagent |
Key Features of Mercurous Chloride
- Mercurous Chloride belongs to the class of mercury-containing inorganic laboratory substances.
- Its chemical identity is associated with electrochemical reference electrodes and the distinction between mercury(I) and mercury(II).
- An important scientific characteristic is the stable chloride-containing solid phase used in saturated calomel electrode systems.
- Reagent selection requires matching the chemical form and method-specific requirements.
- Handling must address mercury handling restrictions despite its low aqueous solubility.
Laboratory Applications of Mercurous Chloride
- Studying the principle of saturated calomel reference electrodes.
- Investigating mercury(I) versus mercury(II) oxidation states.
- Examining low-solubility chloride equilibria in inorganic research.
- Characterizing the dimercury cation using specialized methods.
- Comparing historical reference-electrode systems with modern alternatives.
Why Choose Lab Wale to Buy Mercurous Chloride
Lab Wale offers Mercurous Chloride as a laboratory-chemical listing for institutional purchasers, scientific laboratories, universities, and research centres. The 500 gram pack option helps buyers identify the requested purchase quantity. Before ordering, verify that the declared formula, chemical form, grade, and relevant specifications meet the intended method. Review current safety guidance and your institution’s hazardous-material requirements before procurement. Lab Wale product details should support informed selection, not imply guaranteed results or suitability for every laboratory activity.
Frequently Asked Questions About Mercurous Chloride
What is Mercurous Chloride used for in laboratories?
Mercurous Chloride is associated with electrochemical reference electrodes and the distinction between mercury(I) and mercury(II). Actual work should be limited to appropriately equipped laboratories using a validated scientific procedure. Research suitability depends on the reagent identity, the sample matrix, the method, and suitable controls for hazardous mercury-containing materials.
What formula and molecular weight apply to Mercurous Chloride?
The relevant formula is Hg2Cl2, with a stated mass of 472.08 g/mol. Where hydration or form is unspecified, these values describe the noted composition rather than a confirmed commercial lot. Identify the precise supplied form before carrying out any stoichiometric calculations.
What CAS number identifies Mercurous Chloride?
The relevant chemical registry information is 10112-91-1. A CAS number must refer to the actual chemical identity, not merely a related salt or hydrate. Inspect the supplied label and safety documentation whenever the catalog name leaves the exact chemical form uncertain.
Can Mercurous Chloride be used in school or college laboratories?
Because mercury compounds pose significant health and environmental hazards, this material should not be assumed suitable for ordinary school practicals. Specialized educational or research applications require formal risk assessment, qualified supervision, effective exposure controls, and regulated collection of mercury-containing waste.
How should Mercurous Chloride be stored and handled?
Keep the material in a securely closed, compatible and clearly labelled container in a restricted hazardous-chemical storage area. Avoid dust, splashes, incompatible reagents, and uncontrolled heating. Review the current Safety Data Sheet, wear suitable protective equipment, and use a fume hood or equivalent containment where necessary.
Storage Conditions for Mercurous Chloride
Store Mercurous Chloride in a tightly closed, chemically compatible and clearly labelled container within a locked or access-controlled toxic-substance area. Use suitable secondary containment, prevent dust escape, and protect the product from unintended heat and incompatible chemicals. Follow the current Safety Data Sheet for any form-specific sensitivity to light, moisture, or oxidizing and reducing agents.
Precautions for Handling Mercurous Chloride
Review the current Safety Data Sheet and a task-specific mercury exposure assessment before handling Mercurous Chloride. Only trained personnel should use the reagent with appropriate protective gloves, laboratory eyewear, protective clothing, and effective containment or a fume hood as required. Avoid inhalation, ingestion, skin contact, dust generation, and environmental release. Keep all contaminated equipment, residues, and spill absorbents out of ordinary drains and waste streams; follow approved mercury-waste and emergency procedures.


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